Thursday, March 18, 2010

Rock climber takes on surfer's theory


By Carol Clark

The “exceptionally simple theory of everything,” proposed by a surfing physicist in 2007, does not hold water, says Emory mathematician Skip Garibaldi.

Garibaldi, a rock climber in his spare time, did the math to disprove the theory, which involves a mysterious structure known as E8. The resulting paper, co-authored by physicist Jacques Distler of the University of Texas, will appear in an upcoming issue of Communications in Mathematical Physics.

"The beautiful thing about math and physics is that it is not subjective," Garibaldi says. "I wanted a peer-reviewed paper published, so that the scientific literature provides an accurate state of affairs, to help clear up confusion among the lay public on this topic."

In November of 2007, physicist Garrett Lisi published an online paper entitled “An Exceptionally Simple Theory of Everything.” Lisi spent much of his time surfing in Hawaii, adding an alluring bit of color to the story surrounding the theory. Although his paper was not peer-reviewed, and Lisi himself told the Daily Telegraph that the theory was still in development and he gave a "low" likelihood to the prediction, the idea was widely reported in the media, under attention-grabbing headlines like “Surfer dude stuns physicists with theory of everything.”

Garibaldi was among the skeptics when the theory hit the news. So was Distler, a particle physicist, who wrote about problems he saw with Lisi’s idea on his blog. Distler’s posting inspired Garibaldi to think about the issue more, eventually leading to their collaboration.

Lisi’s paper centered on the elegant mathematical structure known as E8, which also appears in string theory. First identified in 1887, E8 has 248 dimensions and cannot be seen, or even drawn, in its complete form.E8-inspired graph. Credit: Wikimedia Commons, J. G. Moxness, an emulation of a hand-drawn original by Peter McMullen.

The enigmatic E8 is the largest and most complicated of the five exceptional Lie groups, and contains four subgroups that are related to the four fundamental forces of nature: the electromagnetic force; the strong force (which binds quarks); the weak force (which controls radioactive decay); and the gravitational force.

In a nutshell, Lisi proposed that E8 is the unifying force for all the forces of the universe.

“That would be great if it were true, because I love E8,” Garibaldi says. “But the problem is, it doesn’t work as he described it in his paper.”

As a leading expert on several of the exceptional Lie groups, Garibaldi felt an obligation to help set the record straight.

"A lot of mystery surrounds the Lie groups, but the facts about them should not be distorted," he says. "These are natural objects that are central to mathematics, so it's important to have a correct understanding of them."

Using linear algebra and proving theorems to translate the physics into math, Garibaldi and Distler not only showed that the formulas proposed in Lisi’s paper do not work, they also demonstrated the flaws in a whole class of related theories.

“You can think of E8 as a room, and the four subgroups related to the four fundamental forces of nature as furniture, let’s say chairs,” Garibaldi explains. “It’s pretty easy to see that the room is big enough that you can put all four of the chairs inside it. The problem with ‘the theory of everything’ is that the way it arranges the chairs in the room makes them non-functional.”

He gives the example of one chair inverted and stacked atop another chair.

“I’m tired of answering questions about the ‘theory of everything,’” Garibaldi says. “I’m glad that I will now be able to point to a peer-reviewed scientific article that clearly rebuts this theory. I feel that there are so many great stories in science, there’s no reason to puff up something that doesn’t work.”

Wednesday, March 17, 2010

High school scientists thrive in lab culture


Maza Rose Tchedou, above, a high school senior who has participated in RISE for two years, won a spot in an international science fair with her project, “The Role of Nlp in Drosophila Oogenesis.”

The Research Internship and Science Education (RISE) program gives gifted students from inner-city high schools hands-on experience in the epigenetics lab of biology chair Victor Corces. Since Corces brought RISE to Atlanta three years ago, the program keeps growing and the awards keep coming.

High school freshmen, who see the success of juniors and seniors in RISE, now make getting into RISE one of their goals, says Margaret Rohrbaugh who manages the Corces lab and works closely with the high school teens.

“They are doing true research, studying things that no one has ever looked at before. We help them learn the techniques, but ultimately they are doing the experiments, and they find that exciting.”


Thirteen RISE students competed in the recent metro-Atlanta regional science fairs. “There were about 10 gold keys given out for Atlanta Public Schools and RISE students won half of them,” Rohrbaugh says. The two RISE students competing from Dekalb schools also won gold keys.

The gold key winners continue on to the state science fair in April. Two RISE students also took grand prizes for Atlanta and DeKalb schools, giving them the chance to compete in an international science fair in San Jose, California, this May.

Watch a video from last Spring to learn more about RISE:


Related:
RISE teen awarded Gates scholarship

Small steps lead to big career
Teen scientists bloom in lab
Bringing new blood to high school science

Monday, March 15, 2010

What is your baby thinking?

Rio Cros, six months, enjoys the thrill of discovery, whether he's assisting in psychology research or trying a new food. Photo by Carol Clark.

Some of the most valuable minds in research are only a few months old. They belong to the infants who participate in groundbreaking work at the psychology department’s Child Study Center.

How do children learn? What and how do they think and remember? How do children change as they grow older? Families from throughout metro Atlanta are helping scientists at the Child Study Center explore these questions and more.

“This is a volunteer activity, and it’s impressive to me the number of families that are willing to come in and give their time for the greater good of science,” says Kelly Yates, Child Study Coordinator.

“I strongly believe in promoting research and the understanding of human development,” says Jill Woodard, a manager of research projects at the Rollins School of Public Health, who recently brought in her 9-month-old son, Bennie, to participate in a study. “I think it helped me understand my son better and how he interacts with the world,” she adds.

The center seeks participants ranging in age from newborns to adolescence. The number of children needed to complete a single study can range from 30 to 300. "All of the information in parenting books and child development textbooks comes from these kinds of studies," says Ayzit Doydum, a lab manager for Patricia Bauer at the center. "We're really grateful to the families who participate. We couldn't do our jobs without them."

Watch the video to learn more.


Related:
How babies use number, space and time
First blush: When babies get embarrassed
How we learn language

Stories your parents should have told you

Friday, March 12, 2010

Water oxidation advance aims at solar fuel


Liquid sunlight: Bubbles form during water oxidation, catalyzed by the new tetra-cobalt WOC. Photo by Benjamin Yin.

Emory chemists have developed the most potent homogeneous catalyst known for water oxidation, considered a crucial component for generating clean hydrogen fuel using only water and sunlight. The breakthrough, to be published in the journal Science, was made in collaboration with the Paris Institute of Molecular Chemistry.

The fastest, carbon-free molecular water oxidation catalyst (WOC) to date "has really upped the standard from the other known homogeneous WOCs," said Emory inorganic chemist Craig Hill, whose lab led the effort. "It's like a home run compared to a base hit."

In order to be viable, a WOC needs selectivity, stability and speed. Homogeneity is also a desired trait, since it boosts efficiency and makes the WOC easier to study and optimize. The new WOC has all of these qualities, and it is based on the cheap and abundant element cobalt, adding to its potential to help solar energy go mainstream.

Benjamin Yin, an undergraduate student in Hill’s lab, is the lead author on the Science paper. Emory chemists who are co-authors include Hill, Yurii Gueletii, Jamal Musaev, Zhen Luo and Ken Hardcastle. The U.S. Department of Energy funded the work.

The WOC research is a component of the Emory Bio-inspired Renewable Energy Center, which aims to mimic natural processes such as photosynthesis to generate clean fuel. The next step involves incorporating the WOC into a solar-driven, water-splitting system.

The long-term goal is to use sunlight to split water into oxygen and hydrogen. Hydrogen becomes the fuel. Its combustion produces the by-product of water – which flows back into a clean, green, renewable cycle.Three main technical challenges are involved: developing a light collector, a catalyst to oxidize water to oxygen and a catalyst to reduce water to hydrogen. All three components need improvement, but a viable WOC may be the most difficult scientific challenge. “We are aiming for a WOC that is free of organic structure, because organic components will combine with oxygen and self-destruct,” Hill says. “You’ll wind up with a lot of gunk.”

Enzymes are nature’s catalysts. The enzyme in the oxygen-evolving center of green plants “is about the least stable catalyst in nature, and one of the shortest lived, because it’s doing one of the hardest jobs,” Hill says.

"We've duplicated this complex natural process by taking some of the essential features from photosynthesis and using them in a synthetic, carbon-free, homogeneous system. The result is a water oxidation catalyst that is far more stable than the one we found in nature."

For decades, scientists have been trying to imitate Mother Nature and create a WOC for artificial photosynthesis. Nearly all of the more than 40 homogeneous WOCs developed by labs have had significant limitations, such as containing organic components that burn up quickly during the water oxidation process.

Two years ago, Hill’s lab and collaborators developed the first prototype of a stable, homogenous, carbon-free WOC, which also worked faster than others known at the time. The prototype, however, was based on ruthenium, a relatively rare and expensive element.

Building on that work, the researchers began experimenting with the cheaper and more abundant element cobalt. The cobalt-based WOC has proved even faster than the ruthenium version for light-driven water oxidation.

Related:
Bringing new energy to solar quest
Shining a light on green energy
Chemistry's crucial catalyst
Doing chemistry with the sun

Thursday, March 11, 2010

Bringing new energy to solar quest


The search for clean, cheap energy sources is the biggest problem of our age, says chemist Brian Dyer, director of the Emory Bio-inspired Renewable Energy Center (EBREC). eScienceCommons interviewed Dyer about how the new center is carving out a unique niche in the development of solar energy solutions, through its work at the intersection of chemistry, physics and biology, and its outreach to the broader community.

Q: How is EBREC tackling the technical problems of clean energy?

Dyer: We want to create a completely green, cheap and sustainable energy cycle, using just sunlight and water to generate hydrogen fuel. We are trying to mimic the way that plants use photosynthesis to capture sunlight and store it as fuel, and also harness the power of anaerobic bacteria to generate hydrogen.

Q. Is Emory competitive with other institutions at work on these problems?

Dyer: Emory brings together leading expertise in key areas: quantum dot technology, to absorb light and drive reactions; water oxidation catalysis, to split water into oxygen and protons; microbial catalysis by the protein hydrogenase, to convert protons into hydrogen; and protein re-engineering, to evolve the needed properties in hydrogenase.

All of these areas need a lot more refinement in order to cheaply and efficiently produce hydrogen fuel, but a water oxidation catalyst, or WOC, is considered the most difficult and crucial piece of the puzzle. Craig Hill’s inorganic chemistry lab just led the development of the best homogeneous WOC known, with the highest potential for getting hydrogen fuel from water, using only solar energy. This breakthrough puts Emory and our energy center in a very strong position.

Emory has a good track record of bringing together interdisciplinary teams, and tremendous strengths in the biological sciences, as well as the physical sciences. Most of the advances in renewable energy are going to be made at that interface.

But we’re not just a bunch of nerdy scientists tinkering in our labs. We’re thinking about the human implications of our work.

Q. How do you view your role beyond the lab?

Dyer: We realize that renewable energy is much more than just a science problem. It’s a political problem, an economic problem, an environmental problem, a health problem, a cultural problem and even a peace problem.

EBREC needs to engage resources throughout the University to further the cause of clean energy, as well as local, national and international communities. You can come up with great technology, but it doesn’t do any good if you don’t change the way people think. We need political will, economic incentives and public outreach to help people understand that our collective future depends on clean, renewable energy.

So in addition to building on our foundation of interdisciplinary science, EBREC plans to leverage Emory’s tremendous strengths in community engagement and global initiatives that span disciplines.

Q: How urgent is this issue?

Dyer: Energy underlies everything, from the quality of our daily lives, to our industrial capacity, our transportation and our security. Our current worldwide energy use is equivalent to about 100 billion 100-watt light bulbs that are on all the time: 24/7, 365 days of the year. Our energy use is expected to double within the next 40 years. So how are we going to get there without running out of fossil fuels, further warming our climate and destroying the environment?

While the United States is distracted by the health care debate, China is building coal-fired plants as fast as it can. At the same time, China is investing billions of dollars in renewable energy technology, in an attempt to dominate that market. In 10 years, I believe that it will. The United States is falling behind in this critical area, which in the long run could endanger our economy as well as the fate of the planet.

It’s going to take an enormous collective effort to solve the scientific and social problems surrounding renewable energy. EBREC is working to make a difference in both of these areas.

Related:
Water oxidation advance aims at solar fuel
A biochemical path to solar energy
Shining a light on green energy
Chemistry's crucial catalyst